On top of being a couple that I’d love to have seen happen, Gin and Matsumoto were somewhat unusual together. As Gin was a captain and worked for Aizen for most of his life, he learnt one thing to which Aizen was up to no good at all. He dedicated his life to watching over Aizen until the very end when Rangiku herself couldn’t understand why he had done so, she wanted him so badly.
The impressive artwork above was created by AnimeZona who has a great deal of fantastic artwork based on anime’s such as Bleach and Fairy Tail. They are pretty cool, thus you should go and check them out. On top of which you should share the page for other fans to see.